Reaction selectivity of homochiral versus heterochiral intermolecular reactions of prochiral terminal alkynes on surfaces
oleh: Tao Wang, Haifeng Lv, Jianmin Huang, Huan Shan, Lin Feng, Yahui Mao, Jinyi Wang, Wenzhao Zhang, Dong Han, Qian Xu, Pingwu Du, Aidi Zhao, Xiaojun Wu, Steven L. Tait, Junfa Zhu
| Format: | Article |
|---|---|
| Diterbitkan: | Nature Portfolio 2019-09-01 |
Deskripsi
Controlling selectivity between homochiral and heterochiral reaction pathways on surfaces is intriguing but challenging. Here, the authors demonstrate strategies in steering the reactions of prochiral terminal alkynes between the homochiral and heterochiral pathways by tuning the precursor substituents and the kinetic parameters.