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Pt/Mesoporous Carbon Counter Electrode with a Low Pt Loading for High-Efficient Dye-Sensitized Solar Cells
oleh: Guiqiang Wang, Junfeng Gu, Shuping Zhuo
| Format: | Article |
|---|---|
| Diterbitkan: | Wiley 2010-01-01 |
Deskripsi
Pt/Mesoporous carbon counter electrodes with a low Pt loading for dye-sensitized solar cells were fabricated by coating Pt/mesoporous carbon on fluorine-doped tin oxide glass. Pt/mesoporous carbon samples were prepared by reducing H2PtCl6 with NaBH4 in mesoporous carbon and characterized by N2 adsorption analysis, X-ray diffraction, X-ray photoelectron spectroscopy, and transmission electron microscopy. The Pt particles deposited on mesoporous carbon support were found to be in uniform shape and narrow range of particle size. Low-Pt-loading Pt/mesoporous carbon counter electrode showed a high electrocatalytic activity for triiodide reduction. Electrochemical impedance spectroscopy measurement displayed a low charge-transfer resistance of 1.2 Ωcm2 for 1-Pt/mesoporous carbon counter electrode. Dye-sensitized solar cells based on the 1-Pt/mesoporous carbon counter electrode achieved an overall conversion efficiency of 6.62% under one sun illumination, which is higher than that of the cell with the conventional Pt counter electrode.