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The title compound, (C2H8N)(C5H12NO)[ZnCl4], was synthesized by hydrothermal reaction of ZnCl2 with 4-methylmorpholine in a dimethylformamide solution. The asymmetric unit is composed of half a [ZnCl4]2− anion, half a 4-methylmorpholin-4-ium cation and half a dimethylammonium cation, all located on mirror planes parallel to ac. All the amine H atoms are involved in intermolecular N—H...Cl hydrogen bonds, building up an infinite chain parallel to the c axis.