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Herein, reduced graphene-oxide-supported ZrO₂ and Y₂O₃ (rGO-ZrO₂ and rGO-Y₂O₃) nanocomposites were synthesized by hydrothermal method and used as the catalysts for photodegradation of picric acid. The structural and morphological properties of the synthesized samples were characterized by using an X-ray diffractometer (XRD), scanning electron microscope (SEM) with energy dispersive absorption X-ray spectroscopy (EDAX), UV-Vis spectrophotometer, Raman spectrophotometer and Fourier transformation infrared spectrophotometer (FT-IR) techniques. In this work, the wide band gap of the ZrO₂ and Y₂O₃ was successfully reduced by addition of the reduced graphene oxide (rGO) to absorb visible light for photocatalytic application. The performance of as synthesized rGO-ZrO₂ and rGO-Y₂O₃ nanocomposites in the photocatalytic degradation of picric acid were evaluated under UV light irradiation. The photodegradation study using picric acid was analyzed with different energy light sources UV (254, 365 and 395 nm), visible light and sunlight at different pH conditions (pH = 3, 7 and 10). The photocatalytic activity of rGO-ZrO₂ and rGO-Y₂O₃ nanocomposites showed excellent photocatalytic activity under optimum identical conditions with mild variations in pH 3. Compared to rGO-Y₂O₃, the rGO-ZrO₂ nanocomposite showed a better action, with a degradation percentage rate of 100, 99.3, 99.9, 100 and 100% for light conditions of UV-252, 365, 395, visible and sunlight, respectively. The excellent degradation efficiency is attributed to factors such as oxygen-deficient metal oxide phase, high surface area and creation of a greater number of hydroxyl groups.