Bis(2-aminobenzothiazol-3-ium) bis(7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato-κ3O2,O3,O7)nickelate(II) hexahydrate

oleh: Fan Zhang, Gui-Xian Wang, Qi-Wei Zhang

Format: Article
Diterbitkan: International Union of Crystallography 2012-05-01

Deskripsi

In the title compound, (C7H7N2S)2[Ni(C8H8O5)2]·6H2O, the NiII cation is located on an inversion center and is O,O′,O′′-chelated by two symmetry-related 7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylate anions in a distorted octahedral geometry. The 2-aminobenzothiazol-3-ium cation links with the Ni complex anion via N—H...O hydrogen bonding. Extensive O—H...O and N—H...O hydrogen bonds involving the lattice water molecules also occur in the crystal structure.