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This paper aims to present some results about the calorific properties of biomass wastes from exotic species used as fuels. There are presented the main characteristics of biomass energy, respectively the low and high calorific value, burning speed and energy efficiency. Methodology takes into consideration the equipment, wooden species and relationships for calorific determination. The final conclusion resulting from the experiments is that the biomass of exotic species is as good as any other woody biomass, when is used as fuel, because the calorific properties are closely, even slightly higher than of classical fuels.