Diazidobis(2,2′-biimidazole)cobalt(II)

oleh: Sheng Li, Shou-Bin Wang, Fu-Li Zhang, Kun Tang

Format: Article
Diterbitkan: International Union of Crystallography 2008-01-01

Deskripsi

In the title compound, [Co(N3)2(C6H6N4)2], the CoII atom lies on a centre of inversion and is bonded to two azide ions and two bidentate 2,2′-biimidizole ligands, giving a slightly distorted octahedral CoN6 coordination geometry. In the crystal structure, intermolecular N—H...N hydrogen bonds exist between the 2,2′-biimidizole ligands and the azide ions, linking the complexes into sheets.