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Study of the Surface-Layer Softening Effects in xLi<sub>2</sub>ZrO<sub>3</sub>–(1−x)Li<sub>4</sub>SiO<sub>4</sub> Ceramics under Irradiation with He<sup>2+</sup> Ions
oleh: Dmitriy I. Shlimas, Daryn B. Borgekov, Kayrat K. Kadyrzhanov, Artem L. Kozlovskiy, Maxim V. Zdorovets
| Format: | Article |
|---|---|
| Diterbitkan: | MDPI AG 2024-04-01 |
Deskripsi
The study investigates alterations in the mechanical and thermophysical properties of ceramics composed of xLi<sub>2</sub>ZrO<sub>3</sub>–(1−x)Li<sub>4</sub>SiO<sub>4</sub> as radiation damage accumulates, mainly linked to helium agglomeration in the surface layer. This research is motivated by the potential to develop lithium-containing ceramics characterized by exceptional strength properties and a resistance to the accumulation of radiation damage and ensuing deformation distortions in the near-surface layer. The study of the radiation damage accumulation processes in the near-surface layer was conducted through intense irradiation of ceramics using He<sup>2+</sup> ions at a temperature of 700 °C, simulating conditions closely resembling operation conditions. Following this, a correlation between the accumulation of structural modifications (value of atomic displacements) and variations in strength and thermophysical characteristics was established. During the research, it was observed that two-component ceramics exhibit significantly greater resistance to external influences and damage accumulation related to radiation exposure compared to their single-component counterparts. Furthermore, the composition that provides the highest resistance to softening in two-component ceramics is an equal ratio of the components of 0.5Li<sub>2</sub>ZrO<sub>3</sub>–0.5Li<sub>4</sub>SiO<sub>4</sub> ceramics.