The monoclinic form of di-μ-aqua-bis[diaquabis(thiocyanato-κN)iron(II)]–1,4-bis(4H-1,2,4-triazol-4-yl)benzene (1/3)
oleh: Yuan-Yuan Liu, Pan Yang, Bin Ding
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2012-08-01 |
Deskripsi
The title complex, [Fe2(NCS)4(H2O)6]·3C10H8N6, comprises two FeII atoms octahedrally coordinated and bridged by two aqua O atoms that straddle a crystallographic inversion center, forming a quadrilateral core. The water ligands of the core are involved in hydrogen bonds with the triazole N atoms of the organic molecules, which generates a layer motif in the ab plane. There are π–π stacking interactions between benzene rings of 3.490 (6) Å, and between triazole rings of 3.543 (8) and 3.734 (7) Å in neighboring layers, forming a three-dimensional network.