Density, Viscosity and Free Energy of Activation for Viscous Flow of Monoethanol Amine (1) + H<sub>2</sub>O (2) + CO<sub>2</sub> (3) Mixtures

oleh: Sumudu S. Karunarathne, Dag A. Eimer, Lars E. Øi

Format: Article
Diterbitkan: MDPI AG 2020-01-01

Deskripsi

Densities and viscosities of aqueous monoethanol amine (MEA) and CO<sub>2</sub>-loaded aqueous MEA are highly relevant in engineering calculations to perform process design and simulations. Density and viscosity of the aqueous MEA were measured in the temperature range of 293.15 K to 363.15 K with MEA mass fractions ranging from 0.3 to 1.0. Densities of the aqueous MEA were fitted for a density correlation. Eyring&#8217;s viscosity model based on absolute rate theory was adopted to determine the excess free energy of activation for viscous flow of aqueous MEA mixtures and was correlated by a Redlich&#8722;Kister polynomial. Densities and viscosities of CO<sub>2</sub>-loaded MEA solutions were measured in the temperature range of 293.15 K to 353.15 K with MEA mass fractions of 0.3, 0.4 and 0.5. The density correlation used to correlate aqueous MEA was modified to fit CO<sub>2</sub>-loaded density data. The free energy of activation for viscous flow for CO<sub>2</sub>-loaded aqueous MEA solutions was determined by Eyring&#8217;s viscosity model and a correlation was proposed to represent free energy of activation for viscous flow and viscosity. This can be used to evaluate quantitative and qualitative properties in the MEA + H<sub>2</sub>O + CO<sub>2</sub> mixture.