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2.5D woven composites have been increasingly used in aerospace and military applications due to their excellent mechanical properties. In this research, 2.5D woven composites were produced, and their compression responses were investigated in different directions by compression experiments. XR-CT (X-ray computed tomography) technology was used to observe the microstructural damage profiles, and to analyze the failure mechanism of the material. The results show that when subjected to compression loads, the maximum load-bearing capacity of the material in the thickness direction was better than the maximum load-bearing capacity in the warp and weft directions. The compressive strength of the material in the warp and weft directions was lower than that in the thickness direction, and compression damage patterns in each direction also differed.