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(2,2′-Bipyridyl)bis[N-(2-hydroxyethyl)-N-n-propyldithiocarbamato-κ2S,S′]cadmium(II) acetonitrile solvate
oleh: Edward R. T. Tiekink, Juyoung C. Song
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2009-12-01 |
Deskripsi
The title complex, [Cd(C6H12NOS2)2(C10H8N2)]·CH3CN, features a distorted octahedral N2S4 geometry for the CdII centre defined by a pair of asymmetrically chelating dithiocarbamate ligands as well as a 2,2′-bipyridine ligand. Supramolecular chains along [001] are formed in the crystal structure, mediated by O—H...S hydrogen bonds; the acetonitrile solvent molecules are associated with the chains via O—H...N hydrogen bonds.