(Acetylacetonato-κ2O,O′)bis[2-(5-methyl-3-phenylpyrazin-2-yl-κN1)phenyl-κC1]iridium(III)
oleh: Xiao-Nan Xu, Mao-He Li, Cheng-Hao Gu, Guo-Ping Ge, Chun-Yan Li
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2012-03-01 |
Deskripsi
In the title complex, [Ir(C17H13N2)2(C5H7O2)], the IrIII atom is hexacoordinated in a distorted octahedral geometry by two C,N-bidentate 2-(5-methyl-3-phenylpyrazin-2-yl)phenyl (mdpp) ligands and one O,O-bidentate acetylacetonate ligand. The dihedral angles between the phenyl rings and the pyrazine ring are 9.56 (14) and 58.99 (14)° for one mdpp ligand and 9.34 (14) and 79.94 (15)° for the other.