Find in Library
Search millions of books, articles, and more
Indexed Open Access Databases
Measurements of N<sub>2</sub>, CO<sub>2</sub>, Ar, O<sub>2</sub> and Air Pressure Broadening Coefficients of the HCl P(5) Line in the 1–0 Band Using an Interband Cascade Laser
oleh: Zhechao Qu, Javis A. Nwaboh, Gang Li, Olav Werhahn, Volker Ebert
Format: | Article |
---|---|
Diterbitkan: | MDPI AG 2021-06-01 |
Deskripsi
We determine the CO<sub>2</sub>, N<sub>2</sub>, Ar, O<sub>2</sub> and air pressure broadening coefficients of the H<sup>35</sup>Cl P(5) absorption line at 2775.77 cm<sup>−1</sup> in the fundamental (1←0) band using a newly developed direct tunable diode laser absorption spectroscopy (dTDLAS)-based spectrometer employing a mid-IR interband cascade laser (ICL). For the first time, a reliable and consistent set of five different foreign pressure broadening coefficients for the same HCl P(5) line has been measured by a consistent metrological approach covering pressures from 100 to 600 hPa at temperatures of 294 and 295 K. The relative uncertainties of the stated CO<sub>2</sub>, N<sub>2</sub>, Ar, O<sub>2</sub> and Air pressure broadening coefficients are in 1–3% range. The results are compared to previously available literature data—two broadening coefficients have been improved in accuracy and two have been determined for the first time in the sub 1000 hPa pressure range.