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A hierarchical controller including a vehicle condition parameter estimator for improving the vehicle stability is theoretically applied to a four-wheel independent-drive electric vehicle. This study is aimed at combining the parameters estimation with vehicle stability control and evaluating different optimization algorithms based on the computation time and fluctuation. The hierarchical controller consists of a vehicle condition parameter estimator, active yaw moment controller, and torque distribution controller. The vehicle condition parameter estimator is based on the Unscented Kalman Filter, which avoids the truncation error caused by Taylor expansion to convert a nonlinear system into a linear system. The active yaw moment controller is designed based on the sliding mode control. The controller employs co-control between the vehicle sideslip angle and yaw rate, which properly accounts for both factors. The objective function of the torque distribution controller is based on the tire utilization function and constraint condition. The torque distribution and wheel slip rate are accounted for simultaneously. The torque distribution methods are tested based on nonlinear programming, quadratic programming, and weighted least squares for the sake of comparison. The simulation results demonstrate the accuracy of the proposed vehicle state estimator and the effectiveness of the proposed stability controller.