{meso-Tetrakis[p-(heptyloxy)phenyl]porphyrinato}silver(II)
oleh: Jun-Xu Liao, Hong-Bin Zhao, De-Liang Yang, Liang Chen, Bang-Ying Wang
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2011-09-01 |
Deskripsi
The title compound, [Ag(C72H84N4O4)], crystallizes with the AgII cation on a centre of symmetry. The macrocyclic 24-membered ring core is planar with a mean deviation of 0.0311 (15) Å and the four-coordinate AgII cation fits into its center, at 2.0814 (19) and 2.0872 (19) Å, from the surrounding pyrrole-N atoms, in agreement with what is found in related compounds. The p-heptyloxyphenyl groups are rotated 75.51 (5) and 84.45 (8)° with respect to the porphyrin mean plane, due to steric hindrance with the pyrrole-H atoms of the macrocycle.