Bis[2-(aminomethyl)pyridine-κ2N,N′]bis(thiocyanato-κN)copper(II)
oleh: Hon Man Lee, Kai-Ting Chan, Nirmal Kumar Karan
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2009-05-01 |
Deskripsi
In the title complex, [Cu(NCS)2(C6H8N2)2], the CuII atom, lying on an inversion center, adopts a Jahn–Teller distorted octahedral CuN6 coordination geometry. The two bidentate 2-aminomethylpyridine ligands are coordinated in a trans fashion, while the two thiocyanate ligands are at the axial positions and coordinate to the Cu atom in a bent mode with a C—N—Cu angle of 127.49 (10)°. Intermolecular N—H...N and N—H...S hydrogen bonds link the copper complex molecules into an infinite two-dimensional network.