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Identifying Oxide and CaS Non-Metallic Inclusions in Steel with Raman Spectroscopy
oleh: Francis Gyakwaa, Tuomas Alatarvas, Qifeng Shu, Timo Fabritius
| Format: | Article |
|---|---|
| Diterbitkan: | MDPI AG 2022-12-01 |
Deskripsi
Identification and characterization play an essential role in the study of non-metallic inclusions (NMIs) in monitoring the steel casting process and product quality. This study uses Raman spectroscopy, a versatile, relatively fast, and non-destructive technique for characterizing oxide and sulfide-based inclusion phases in steel samples. The relative Raman peak intensities and positions were used to qualitatively estimate the inclusion phases of Al<sub>2</sub>O<sub>3</sub>, CA, C12A7, C3A, MgO·Al<sub>2</sub>O<sub>3</sub>, and CaS. For a quantitative estimation, FESEM-EDS (field emission scanning electron microscope with energy dispersive X-ray spectroscopy) was used to evaluate the inclusion phases in the samples. This study demonstrates that Raman spectroscopy can be used to rapidly estimate the content of Al<sub>2</sub>O<sub>3</sub>, magnesium aluminate spinel (MgO·Al<sub>2</sub>O<sub>3</sub>), and the calcium aluminate phases of CA, C3A, and C12A7 in steel samples to complement established characterization techniques for NMIs analysis such as FESEM-EDS.