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Poly[[triaqua(μ3-4-oxidopyridine-2,6-dicarboxylato)holmium(III)] monohydrate]
oleh: Zhu-Qing Gao, Dong-Yu Lv, Jin-Zhong Gu, Hong-Jin Li
Format: | Article |
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Diterbitkan: | International Union of Crystallography 2011-06-01 |
Deskripsi
In the title coordination polymer, {[Ho(C7H2NO5)(H2O)3]·H2O}n, the HoIII atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxylate trianion, two monodentate anions and three water molecules, forming a distorted bicapped trigonal–prismatic HoNO7 coordination geometry. The anions bridge adjacent HoIII ions into double chains. Adjacent chains are further connected into sheets. O—H...O hydrogen bonds involving both coordinated and uncoordinated water molecules generate a three-dimensional supramolecular framework.