Phosphines featuring a hexafluorocyclopentene skeleton: Synthesis, coordination properties, and applications for Lewis-acidic transition-metal catalysts
oleh: Tomohiro Agou, Nao Wada, Momoko Komatsu, Miki Nohara, Yoshiyuki Mizuhata, Norihiro Tokitoh, Takaaki Hosoya, Hiroki Fukumoto, Toshio Kubota
| Format: | Article |
|---|---|
| Diterbitkan: | Elsevier 2019-01-01 |
Deskripsi
Weakly σ-donating phosphines bearing a hexafluorocyclopentene skeleton were synthesized. The 1JPSe coupling constants of selenides of the fluorinated phosphines revealed substantially decreased s-character of the phosphorus lone pair orbitals of the fluorinated phosphines, indicating their weak σ-donating ability. Au(I), Pd(II) and Pt(II) complexes bearing the fluorinated phosphines showed moderate catalytic activity in the hydration and hydroarylation of alkynes.