[2,6-Bis(6-methylquinolin-2-yl)pyridine-κ3N,N′,N′′]dichloridomanganese(II)
oleh: Seik Weng Ng, Jian-She Zhao, Xiao-Ping Li
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2010-10-01 |
Deskripsi
In the molecule of the title compound, [MnCl2(C25H19N3)], the three N atoms span the axial–equatorial–axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the MnII atom is 34% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pathway). One of the Cl atoms is disordered over two positions in a 0.82 (3):0.18 (3) ratio. Weak intermolecular C—H...Cl hydrogen bonding occurs in the crystal structure.