Poly[[μ4-naphthalene-1,4-dicarboxylato-κ4O:O′:O′′:O′′′-μ2-naphthalene-1,4-dicarboxylato-κ4O,O′:O′′,O′′′-bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)dimanganese(II)] N,N-dimethylformamide solvate]
oleh: Seik Weng Ng, Mao-Liang Xu, Yang Liu, Heng-Da Li
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2008-05-01 |
Deskripsi
One of the two 1,4-dicarboxylate dianions in the title compound, [Mn2(C12H6O4)2(C19H12N4)2]·C3H7NO, uses its two carboxylate groups to chelate two N-heterocycle-chelated Mn atoms; the other 1,4-dicarboxylate dianion binds to four such metal centers. The octahedrally coordinated Mn atoms are linked through the two dianions into a layer motif; the dimethylformamide molecules occupy the spaces between adjacent layers. Ten C atoms and attached H atoms of one dianion are disordered equally over two positions.