catena-Poly[[(1,10-phenanthroline-κ2N,N′)copper(I)]-μ-thiocyanato-κ2N:S-[(1,10-phenanthroline-κ2N,N′)copper(I)]-μ-cyanido-κ2N:C]
oleh: Xi-Jun Ke, Dong-Sheng Li, Wen-Wen Dong, Jun Zhao
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2008-12-01 |
Deskripsi
In the title complex, [Cu2(CN)(NCS)(C12H8N2)2], which was synthesized under hydrothermal conditions, both CuI atoms have a slightly distorted tetrahedral geometry. They are coordinated by two N atoms of one 1,10-phenanthroline ligand, one bridging thiocyanate anion and one bridging cyanide anion. In the crystal structure, infinite helical {Cu–CN–Cu–SCN}n chains are formed along [{overline 1}01].