Compact, Fast Cavity Ring-Down Spectroscopy Monitor for Simultaneous Measurement of Ozone and Nitrogen Dioxide in the Atmosphere

oleh: Xiaoyan Liu, Zhijing Hu, Hehe Tang, Huijie Xue, Yang Chen, Renzhi Hu

Format: Article
Diterbitkan: MDPI AG 2022-12-01

Deskripsi

A sensitive, compact detector for the simultaneous measurement of O<sub>3</sub> and NO<sub>2</sub> is presented in this work. There are two channels in the detector, namely the O<sub>x</sub> channel and the NO<sub>2</sub> channel. In the presence of excess NO, ambient O<sub>3</sub> is converted to NO<sub>2</sub> in the O<sub>x</sub> measurement channel. In both channels, NO<sub>2</sub> is directly detected via cavity ring-down spectroscopy (CRDS) at 409 nm. At a 10 s integration time, the O<sub>x</sub> and NO<sub>2</sub> channels have a 1σ precision of 14.5 and 13.5 pptv, respectively. The Allan deviation plot shows that the optimal sensitivity of O<sub>3</sub> and NO<sub>2</sub> occurs at an integration time of ~60 s, with values of 10.2 and 8.5 pptv, respectively. The accuracy is 6% for the O<sub>3</sub> channel and 5% for the NO<sub>2</sub> channel, and the largest uncertainty comes from the effective NO<sub>2</sub> absorption cross-section. Intercomparison of the NO<sub>2</sub> detection between the NO<sub>2</sub> and O<sub>x</sub> channels shows good agreement within their uncertainties, with an absolute shift of 0.31 ppbv, a correlation coefficient of R<sup>2</sup> = 0.99 and a slope of 0.98. Further intercomparison for ambient O<sub>3</sub> measurement between the O<sub>3</sub>/NO<sub>2</sub>-CRDS developed in this work and a commercial UV O<sub>3</sub> monitor also shows excellent agreement, with linear regression slopes close to unity and an R<sup>2</sup> value of 0.99 for 1 min averaged data. The system was deployed to measure O<sub>3</sub> and NO<sub>2</sub> concentrations in Hefei, China, and the observation results show obvious diurnal variation characteristics. The successful deployment of the system has demonstrated that the instrument can provide a new method for retrieving fast variations in ambient O<sub>3</sub> and NO<sub>2</sub>.