Bis(N,N-dimethylformamide-κO)bis(1-methylimidazole-2-carbaldehyde oximato-κ2N,O)manganese(III) perchlorate
oleh: Feng Wang, Jianming Zhang, Qirong Wang, Shiying Huang
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2008-11-01 |
Deskripsi
In the title compound, [Mn(C5H6N3O)2(C3H7NO)]ClO4, the MnIII atom lies on the inversion centre of the centrosymmetric complex cation and has a distorted octahedral coordination geometry, formed by two N atoms and two O atoms from two 1-methylimidazole-2-carbaldehyde oximate ligands and two O atoms from two dimethylformamide ligands. Perchlorate acts as a counterion to balance the charge. The crystal structure of the title compound is stabilized by C—H...O hydrogen-bonding interactions.