Bromido{dicyclohexyl[2′-(dimethylamino)biphenyl-2-yl]phosphine-κP}[2-(4,6-dimethylpyrimidin-2-yl)ferrocenyl-κ2C1,N]palladium(II) dichloromethane solvate
oleh: Mao-Ping Song, Yong-Tao Ma, Hui Jiang, Xin-Qi Hao, Hong-Mei Li
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2009-05-01 |
Deskripsi
In the title compound, [FePdBr(C5H5)(C11H10N2)(C26H36NP)]·CH2Cl2, the Pd atom displays a distorted square-planar coordination environment. The five-membered metallacycle adopts an envelope conformation with the coordinated cyclopentadienyl C atom 0.4222 (4) Å out of plane. The dihedral angle between the pyrimidinyl ring and substituted cyclopentadienyl ring is 21.47 (2)°. In the crystal structure, the dimeric unit is generated through the C—H...π contact via a crystallographic inversion centre, while the C—H...Cl contacts in the dimeric centre link the dichlormethane molecules with the Pd complex molecules.