Bis[N,N-bis(diphenylphosphanyl)cyclohexylamine-κ2P,P′]platinum(II) bis(hexafluoridophosphate) dichloromethane disolvate
oleh: Ilana Engelbrecht, Hendrik G. Visser, Andreas Roodt
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2010-08-01 |
Deskripsi
In the title compound, [Pt(C30H31NP2)2](PF6)2·2CH2Cl2, the four-coordinated PtII atom, situated on an inversion centre, exhibits a highly distorted square-planar geometry illustrated by the P—Pt—P bite angle of 70.76 (3)°. The cyclohexyl ring and one of the phenyl rings display 0.630 (7):0.37 (7) and 0.60 (2):0.40 (2) positional disorder, respectively. The dichloromethane solvent molecule displays 0.526 (4):0.474 (4) positional disorder. C—H...F hydrogen bonds stabilize the crystal packing.