Poly[diaquabis(μ-hydrogen benzene-1,2,4-tricarboxylato)copper(II)disodium]: a novel 4,5,6-connected trinodal net
oleh: Annabeth P. Yang, Robert L. LaDuca
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2018-05-01 |
Deskripsi
In the title compound, [CuNa2(C9H4O6)2(H2O)4]n, the CuII cations are square-planar coordinated by carboxylate O-atom donors from four different hydrogen benzene-1,2,4-tricarboxylate (btcH) ligands, thereby forming [Cu(btcH)2]n2n− coordination polymer ribbons. These are connected by octahedrally coordinated and hydrated NaI cations within Na2(μ-H2O)2 clusters to construct the full [Na2(H2O)4Cu(btcH)2]n three-dimensional coordination polymer.