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The article introduces the fractional modified Sprott A chaotic system with its thorough dynamical analysis such as solution of system, Lyapunov dynamics, route to chaos etc. Penta-compound combination anti-synchronization is introduced and applied on twelve chaotic systems of fractional order using adaptive SMC. The system is also controlled about a randomly chosen point and The synchronization technique is illustrated as application to secure communication. The simulations are performed using MATLAB software.