Di-μ-chlorido-bis{[4-amino-3,5-bis(2-pyridyl)-4H-1,2,4-triazole-κN1]chloridomercury(II)}
oleh: Jian Guo, Min Tang, Jing Chen, Cheng-Peng Li
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2011-09-01 |
Deskripsi
In the centrosymmetric binuclear title complex, [Hg2Cl4(C12H10N6)2], the HgII ion is five-coordinated by two N atoms and three chloride ions with a distorted square-pyramidal geometry. In the complex, there is an intramolecular N—H...N hydrogen bond. In the crystal, the binuclear units are connected by intermolecular N—H...Cl hydrogen bonds, as well as π–π stacking interactions [centroid–centroid distances = 3.526 (2) and 3.696 (2) Å], forming a two-dimensional layered structure parallel to (010).