Unveiling a Recycling-Sourced Mineral-Biocellulose Fibre Composite for Use in Combustion-Generated NO<i><sub>x</sub></i> Mitigation Forming Plant Nutrient: Meeting Sustainability Development Goals in the Circular Economy

oleh: Patrick Gane, Katarina Dimić-Mišić, Nemanja Barać, Monireh Imani, Djordje Janaćković, Petar Uskoković, Ernest Barceló

Format: Article
Diterbitkan: MDPI AG 2020-06-01

Deskripsi

NO<i><sub>x</sub></i> is unavoidably emitted during combustion in air at high temperature and/or pressure, which, if exceeding recommended levels, has a negative impact on the population. The authors found that when moist, limestone (CaCO<sub>3</sub>) readily sorbs NO<sub>2</sub> to form calcium nitrate, which provides the basis for developing a surface flow filter. The substrate was made from “over-recycled” cellulose fibres such as newsprint, magazines, or packaging fibre, which are too weak to be used in further recycling. The substrate was specially-coated with fine-ground calcium carbonate and micro-nano-fibrillated cellulose, which was used as a binder and essential humectant to avoid formation of a stagnant air layer. Pre-oxidation countered the action of denitrification bacteria colonising the cellulose substrate. The by-product CO<sub>2</sub> produced in situ during carbonate to nitrate conversion was adsorbed by perlite, which is an inert high surface-area additive. After use, the nitrate-rich CaCO<sub>3</sub>-cellulose-based filter was proposed to be mulched into a run-off resistant soil fertiliser and micronutrient suitable, e.g., for renewable forestry within the circular economy. Belgrade, Serbia, which is a highly polluted city, was used as a laboratory test bed, and NO<sub>2</sub> was successfully removed from an inlet of city air. A construct of street-side self-draughting or municipal/commercial transport vehicle-exterior motion-draught filter boxes is discussed.