Find in Library

New heterotrinuclear complexes with the general formula [Cu₂Ln(H₂L)(HL)(NO₃)₂]·MeOH (Ln = Ho (<b>1</b>), Er (<b>2</b>), <b>H₄L</b> = <i>N</i>,<i>N</i>′-bis(2,3-dihydroxybenzylidene)-1,3-diaminopropane) were synthesized using compartmental Schiff base ligand in conjugation with auxiliary ligands. The compounds were characterized by elemental analysis, ATR-FTIR spectroscopy, X-ray diffraction, TG, DSC, TG-FTIR and XRD analysis. The N₂O₄ salen-type ligand coordinates 3<i>d</i> and 4<i>f</i> metal centers via azomethine nitrogen and phenoxo oxygen atoms, respectively, to form heteropolynuclear complexes having CuO₂Ln cores. In the crystals <b>1</b> and <b>2</b>, two terminal Cu(II) ions are penta-coordinated with a distorted square-pyramidal geometry and a Ln^III ion with trigonal dodecahedral geometry is coordinated by eight oxygen atoms from [Cu^II(H₂L)(NO₃)]⁻ and [Cu^II(HL)(NO₃)]²⁻ units. Compounds <b>1</b> and <b>2</b> are stable at room temperature. During heating, they decompose in a similar way. In the first decomposition step, they lose solvent molecules. The exothermic decomposition of ligands is connected with emission large amounts of gaseous products e.g., water, nitric oxides, carbon dioxide, carbon monoxide. The final solid products of decomposition <b>1</b> and <b>2</b> in air are mixtures of CuO and Ho₂O₃/Er₂O₃. The measurements of magnetic susceptibilities and field dependent magnetization indicate the ferromagnetic interaction between Cu^II and Ho^III ions <b>1</b>.