Amine–borane complex-initiated SF5Cl radical addition on alkenes and alkynes
oleh: Audrey Gilbert, Pauline Langowski, Marine Delgado, Laurent Chabaud, Mathieu Pucheault, Jean-François Paquin
| Format: | Article |
|---|---|
| Diterbitkan: | Beilstein-Institut 2020-12-01 |
Deskripsi
The SF5Cl radical addition on unsaturated compounds was performed using an air-stable amine–borane complex as the radical initiator. This method showed to be complementary to the classic Et3B-mediated SF5Cl addition on alkenes and alkynes. A total of seven alkene and three alkyne derivatives were tested in the reaction, with yields ranging from 3% to 85%.