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The demand for improving the activity, durability, and recyclability of metal-organic cages (MOCs) that work as photocatalytic molecular devices in a homogeneous system has promoted research to combine them with other solid materials. An M₂L₄ type photosensitive metal-organic cage MOC-Q2 with light-harvesting ligands and catalytic Pd²⁺ centers has been synthesized and further heterogenized with graphitic carbon nitride to prepare a robust direct Z-scheme heterojunction photocatalyst for visible-light-driven hydrogen generation. The optimized g-C₃N₄/MOC-Q2 (0.7 wt%) sample exhibits a high H₂ evolution activity of 6423 μmol g⁻¹ h⁻¹ in 5 h, and a total turnover number of 39,695 after 10 h, significantly superior to the bare MOC-Q2 used in the homogeneous solution and the comparison sample Pd/g-C₃N₄/L-4. The enhanced performances of g-C₃N₄/MOC-Q2 can be ascribed to its direct Z-scheme heterostructure, which effectively improves the charge separation and transfer efficiency. This work presents a rational approach of designing a binary photocatalytic system through combing micromolecular MOCs with heterogeneous semiconductors for water splitting.