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Presently, most studies focus on the minimization of the costs and negative social effects of the location of construction waste recycling centers; however, the influence of the location on future operation is usually ignored. Aiming at solving these problems, a location model for the maximization of service reliability was devised. Service reliability includes the recycling reliability of the construction waste and the delivery reliability of the recycled product. Through maximizing service reliability, the location deviation as a result of arrival delay is expected to be reduced and the service reliability improved. Then, two important parameters in our model were solved on the basis of correlative mathematical theories. Finally, an example was implemented to verify our location optimization model. A genetic algorithm was used to obtain optimal solutions, and the solutions were analyzed. Through establishing a location optimization model, a possible better solution to location problems may be obtained to help in implementing location selection for recycling centers.