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In this paper, we present a three-order, divergence-free finite volume scheme to simulate the steady state solar wind ambient. The divergence-free condition of the magnetic field is preserved by the constrained transport (CT) method. The CT method can keep the magnetic fields divergence free if the magnetic fields is divergence free initially. Thus, a least-squares reconstruction of magnetic field with the divergence free constraints is used to make the magnetic fields global solenoidality initially. High order spatial accuracy is obtained through a non-oscillatory hierarchical reconstruction, while a high order time discretization is achieved using a three-order Runge–Kutta scheme. This new model of three order in space and time is validated by numerical results for Carrington rotation 2207. The numerical results show its capability for producing stable reliable results for structured solar wind. The high-order, divergence-free properties of this method make it an ideal tool for the simulations of coronal mass ejection in future.