Bis(tetraphenylphosphonium) bis[N-(phenylsulfonyl)dithiocarbimato-κ2S,S′]platinate(II) monohydrate
oleh: H. A. Silvério, S. Guilardi, Wilson P. Flauzino Neto, Raquel S. Amin, Marcelo R. L. Oliveira
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2010-08-01 |
Deskripsi
The asymmetric unit of the title compound, (C24H20P)2[Pt(C7H5NO2S3)2]·H2O, consists of two tetraphenylphosphonium cations, two half bis[N-(phenylsulfonyl)dithiocarbimato]platinate(II) dianions and one water molecule. The anions are completed by crystallographic inversion symmetry associated with the central PtII ion. The PtII ion is doubly S,S′-chelated by two symmetry-related phenylsulfonyldithiocarbimate ligands, forming a slightly distorted square-planar configuration. Besides the electrostatic attraction between oppositely charged ions in the crystal packing, intramolecular C—H...O and several intermolecular C—H...O, C—H...N and O—H...O hydrogen-bonding interactions between the cations, anions and water molecules are observed.