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Photocatalytic cyclization of nitrogen-centered radicals with carbon nitride through promoting substrate/catalyst interaction
oleh: Mingcheng Yang, Ronghong Lian, Xirui Zhang, Chong Wang, Jiajia Cheng, Xinchen Wang
Format: | Article |
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Diterbitkan: | Nature Portfolio 2022-08-01 |
Deskripsi
Carbon nitride catalysts with positively charged surfaces and abundant −NH2 are found to be effective photocatalysts for dihydropyrazole synthesis. A surface-mediated mechanism where deprotonated intermediates interact with the surface is proposed.