Photocatalytic cyclization of nitrogen-centered radicals with carbon nitride through promoting substrate/catalyst interaction

oleh: Mingcheng Yang, Ronghong Lian, Xirui Zhang, Chong Wang, Jiajia Cheng, Xinchen Wang

Format: Article
Diterbitkan: Nature Portfolio 2022-08-01

Deskripsi

Carbon nitride catalysts with positively charged surfaces and abundant −NH2 are found to be effective photocatalysts for dihydropyrazole synthesis. A surface-mediated mechanism where deprotonated intermediates interact with the surface is proposed.