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Abstract We consider multipartite quantum state discrimination and provide a specific relation between the properties of entanglement witness and quantum nonlocality inherent in the confidence of measurement. We first provide the definition of the confidence of measurement as well as its useful properties for various types of multipartite measurement. We show that globally-maximum confidence that cannot be achieved by local operations and classical communication strongly depends on the existence of a certain type of entanglement witness. We also provide conditions for an upper bound on maximum of locally-achievable confidence. Finally, we establish a method in terms of entanglement witness to construct quantum state ensembles with nonlocal maximum confidence.