Find in Library
Search millions of books, articles, and more
Indexed Open Access Databases
Proton mediated spin state transition of cobalt heme analogs
oleh: Jianping Zhao, Qian Peng, Zijian Wang, Wei Xu, Hongyan Xiao, Qi Wu, Hao-Ling Sun, Fang Ma, Jiyong Zhao, Cheng-Jun Sun, Jianzhang Zhao, Jianfeng Li
Format: | Article |
---|---|
Diterbitkan: | Nature Portfolio 2019-05-01 |
Deskripsi
Studying the electronic structures and spin transitions of synthetic heme analogs is crucial to advancing our understanding of heme enzyme mechanisms. Here the authors show that a Co(II) porphyrin complex undergoes an unexpected spin state transition upon deprotonation of its axial imidazole ligand.