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Ethyl 2-(4-cyanophenyl)-1-(4-fluorobenzyl)-1H-benzo[d]imidazole-5-carboxylate
oleh: S. Madan Kumar, Kumar Vasantha, Poojary Boja, K. Byrappa, Ismail Warad
Format: | Article |
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Diterbitkan: | International Union of Crystallography 2016-07-01 |
Deskripsi
The title benzimidazole derivative, C24H18FN3O2, is T-shaped, with the 4-cyanobenzene and 4-fluorobenzyl rings inclined to the imidazole ring system by 32.89 (10) and 83.63 (10)°, respectively, and by 89.00 (12)° to one another. The terminal methyl group of the ethylcarboxylate group is disordered over three sites and was refined with a fixed occupancy ratio of 1/3:1/3:1/3. In the crystal, molecules are essentially linked by offset π–π interactions, involving inversion-related imidazole rings [inter-centroid distance = 3.763 (1) Å], and stack along the b-axis direction.