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Enhancement of Gamma-ray Shielding Properties in Cobalt-Doped Heavy Metal Borate Glasses: The Role of Lanthanum Oxide Reinforcement
oleh: Ghada ALMisned, Wiam Elshami, Shams A. M. Issa, Gulfem Susoy, Hesham M. H. Zakaly, Merfat Algethami, Y. S. Rammah, Antoaneta Ene, S. A. Al-Ghamdi, Awad A. Ibraheem, H. O. Tekin
| Format: | Article |
|---|---|
| Diterbitkan: | MDPI AG 2021-12-01 |
Deskripsi
The direct influence of La<sup>3+</sup> ions on the gamma-ray shielding properties of cobalt-doped heavy metal borate glasses with the chemical formula 0.3CoO-(80-x)B<sub>2</sub>O<sub>3</sub>-19.7PbO-xLa<sub>2</sub>O<sub>3</sub>: x = 0, 0.5, 1, 1.5, and 2 mol% was examined herein. Several significant radiation shielding parameters were evaluated. The glass density was increased from 3.11 to 3.36 g/cm<sup>3</sup> with increasing La<sup>3+</sup> ion content from 0 to 2 mol%. The S5 glass sample, which contained the highest concentration of La<sup>3+</sup> ions (2 mol%), had the maximum linear (μ) and mass (μ<sub>m</sub>) attenuation coefficients for all photon energies entering, while the S1 glass sample free of La<sup>3+</sup> ions possessed the minimum values of μ and μ<sub>m</sub>. Both the half value layer (T<sub>1/2</sub>) and tenth value layer (TVL) of all investigated glasses showed a similar trend of (T<sub>1/2</sub>, TVL)<sub>S1</sub> > (T<sub>1/2</sub>, TVL)<sub>S2</sub> > (T<sub>1/2</sub>, TVL)<sub>S3</sub> > (T<sub>1/2</sub>, TVL)<sub>S4</sub> > (T<sub>1/2</sub>, TVL)<sub>S5</sub>. Our results revealed that the S5 sample had the highest effective atomic number (Z<sub>eff</sub>) values over the whole range of gamma-ray energy. S5 had the lowest exposure (EBF) and energy absorption (EABF) build-up factor values across the whole photon energy and penetration depth range. Our findings give a strong indication of the S5 sample’s superior gamma-ray shielding characteristics due to the highest contribution of lanthanum oxide.