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Rational design of sulfur hosts for lithium-sulfur (Li-S) batteries is essential to address the shuttle effect and accelerate reaction kinetics. Herein, the composites of bimetallic sulfide CuCo₂S₄ loaded on carbon nanotubes (CNTs) are prepared by hydrothermal method. By regulating the loading of CuCo₂S₄ nanoparticles, it is found that when Cu²⁺ and CNT are prepared in a 10:1 ratio, the CuCo₂S₄ nanoparticles loaded on the CNT are relatively uniformly distributed, avoiding the occurrence of agglomeration, which improves the electrical conductivity and number of active sites. Through a series of electrochemical performance tests, the S/CuCo₂S₄-1/CNT presents a discharge specific capacity of 1021 mAh g⁻¹ at 0.2 C after 100 cycles, showing good cycling stability. Even at 1 C, the S/CuCo₂S₄-1/CNT cathode delivers a discharge capacity of 627 mAh g⁻¹ after 500 cycles. This study offers a promising strategy for the design of bimetallic sulfide-based sulfur hosts in Li-S batteries.