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Nowotny chimney ladder (NCL) phases are intermetallic compounds formed by transition metals and metals of groups 13 and 14. This family can be expanded by combining two <i>p-</i>elements from different groups with those transition metals, for which the corresponding binary NCL phases are unknown. In this paper, we present three new compounds in the V-Al-Ge, Nb-Al-Ge, and Nb-Ga-Ge systems related to the TiSi₂ structure type (Sp. Gr. <i>Fddd</i>) obtained with the standard ampule technique. The crystal structures of the new compounds were determined using synchrotron powder X-ray diffraction data. A transition to the CrSi₂ structure type was detected upon changing the composition from VAl_0.72(2)Ge_1.28(2) to VAl_1.534(3)Ge_0.466(3). According to the 18–<i>n</i> rule, all the compounds are metallic conductors, which was supported by the electronic structure calculations. It was shown that the expected energy gap located above the Fermi level in the vanadium-based NCL compound collapsed into a pseudogap upon the replacement of V by Nb.