How 10 at% Al Addition in the Ti-V-Zr-Nb High-Entropy Alloy Changes Hydrogen Sorption Properties
oleh: Jorge Montero, Gustav Ek, Laetitia Laversenne, Vivian Nassif, Martin Sahlberg, Claudia Zlotea
| Format: | Article |
|---|---|
| Diterbitkan: | MDPI AG 2021-04-01 |
Deskripsi
Al<sub>0.10</sub>Ti<sub>0.30</sub>V<sub>0.25</sub>Zr<sub>0.10</sub>Nb<sub>0.25</sub> was prepared to evaluate the effect of 10% aluminum into the previously reported quaternary alloy, Ti<sub>0.325</sub>V<sub>0.275</sub>Zr<sub>0.125</sub>Nb<sub>0.275</sub>. The as-cast quinary alloy formed a single-phase body centered cubic solid solution and transformed into a body centered tetragonal after hydrogenation. The alloy had a storage capacity of 1.6 H/M (2.6 wt.%) with fast absorption kinetics at room temperature, reaching full capacity within the first 10 min. The major improvements of Al addition (10%) were related to the desorption and cycling properties of the material. The temperature for hydrogen release was significantly decreased by around 100 °C, and the quinary alloy showed superior cycling stability and higher reversible storage capacity than its quaternary counterpart, 94% and 85% of their respective initial capacity, after 20 hydrogenation cycles without phase decomposition.