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This paper introduces a novel approach for solving first-order stiff initial value problems through the development of a one-step family of three optimized second-derivative hybrid block methods. The optimization process was integrated into the derivation of the methods to achieve maximal accuracy. Through a rigorous analysis, it was determined that the methods exhibit properties of consistency, zero-stability, convergence, and A-stability. The proposed methods were implemented using the waveform relaxation technique, and the computed results demonstrated the superiority of these schemes over certain existing methods investigated in the study.