Bis(cyanamide-κN)[4-(1H-imidazol-1-yl)phenol-κN3]bis(nitrato-κO)copper(II)
oleh: Rui-Jin Yu, Bin Deng
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2011-09-01 |
Deskripsi
A pair of linear cyanamide (NCNH2) ligands, two monodentate 4-(1H-imidazol-1-yl)phenol (L) ligands and two nitrate anions link the CuII atom into a mononuclear unit, [Cu(NO3)2(C9H8N2O)2(NCNH2)2]. The coordination polyhedron of the Cu atom is an elongated octahedron distorted by Jahn–Teller effects. Intermolecular O—H...O, O—H...N, N—H...O and N—H...N hydrogen-bonding interactions link these units into a three-dimensional supramolecular architecture.