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Agricultural chemical residue in the environment is one of the biggest concerns for biosafety and human health worldwide. Here, we develop a carrier for pesticides by the chemical combination of UiO-66 and sodium alginate (Alg). When clothianidin (CTD) was encapsulated in UiO-66/Alg, they showed the ability to act as controlled-release pesticides with double stimuli-responsive. Although only 62.74% of CTD was released at 27 °C in 144 h, 93.52% was released at 45 °C at the same time, and the release could be tuned by adding phosphate at the time of greatest requirement. Moreover, the UV-irradiating stability of CTD in UiO-66/Alg was >3.5 times greater than for free CTD, which combined with the outstanding biosafety of UiO-66/Alg-CTD illustrates its potential for development as a bio-friendly, stable and intelligent carrier of pesticides to improve the utilization efficiency of pesticides.