[μ-2,2′-(1,4-Phenylene)diacetato-κ2O1:O4]bis[aqua(2,2′-bipyridine-κ2N,N′)chloridocopper(II)] dihydrate
oleh: Jin-He Zhao, Yan-Xia Lin, Wei Wu, Zhong Zhang
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2012-08-01 |
Deskripsi
In the centrosymmetric title compound, [Cu2(C10H8O4)Cl2(C10H8N2)2(H2O)2]·2H2O, the CuII atom is five-coordinated in a distorted square-pyramidal geometry by two N atoms from a chelating 2,2′-bipyridine ligand, one O atom from a 1,4-phenylenediacetate ligand, one Cl atom and one water molecule. The 1,4-phenylenediacetate ligand, lying on an inversion center, bridges two CuII atoms. In the crystal, O—H...O and O—H...Cl hydrogen bonds and π–π interactions between the pyridine rings [centroid–centroid distance = 3.740 (5) Å] link the complex molecules and uncoordinated water molecules into a three-dimensional network.