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CO<sub>2</sub> in Beijing and Xianghe Observed by Ground-Based FTIR Column Measurements and Validation to OCO-2/3 Satellite Observations
oleh: Minqiang Zhou, Qichen Ni, Zhaonan Cai, Bavo Langerock, Weidong Nan, Yang Yang, Ke Che, Dongxu Yang, Ting Wang, Yi Liu, Pucai Wang
Format: | Article |
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Diterbitkan: | MDPI AG 2022-08-01 |
Deskripsi
Monitoring the atmospheric CO<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>2</mn></msub></semantics></math></inline-formula> columns inside and around a city is of great importance to understand the temporal–spatial variation of XCO<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>2</mn></msub></semantics></math></inline-formula> near strong anthropogenic emissions. In this study, we use two FTIR CO<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>2</mn></msub></semantics></math></inline-formula> column measurements in Beijing (Bruker EM27/SUN) and Xianghe (Bruker IFS 125HR) between 2019 and 2021 to investigate the differences of XCO<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>2</mn></msub></semantics></math></inline-formula> between Beijing (urban) and Xianghe (suburb) in North China and to validate the OCO-2 and OCO-3 satellite XCO<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>2</mn></msub></semantics></math></inline-formula> retrievals. The mean and standard deviation (std) of the <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mo>Δ</mo></semantics></math></inline-formula>XCO<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>2</mn></msub></semantics></math></inline-formula> between Beijing and Xianghe (Beijing–Xianghe) observed by two FTIR instruments are 0.206 ± 1.736 ppm, which has a seasonal variation and varies with meteorological conditions (wind speed and wind direction). The mean and std of the XCO<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>2</mn></msub></semantics></math></inline-formula> differences between co-located satellite and FTIR measurements are −0.216 ± 1.578 ppm in Beijing and −0.343 ± 1.438 ppm in Xianghe for OCO-2 and 0.637 ± 1.594 ppm in Beijing and 1.206 ± 1.420 ppm in Xianghe for OCO-3. It is found that the OCO-3 snapshot area mode (SAM) measurements can capture the spatial gradient of XCO<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>2</mn></msub></semantics></math></inline-formula> between urban and suburbs well. However, the FTIR measurements indicate that the OCO-3 SAM measurements are about 0.9–1.4 ppm overestimated in Beijing and Xianghe.